Bài 17 : Silic và hợp chất của silic

Bài 6 (trang 79 SGK Hóa 11): Cho hỗn hợp silic và than có khối lượng 20,0g tác dụng với lượng dư dung dịch NaOH đặc, đun nóng. Phản ứng giải phóng ra 13,44 lít khí hidro (đktc)Xác định thành phần phần trăm khối lượng của silic trong hỗn hợp ban đầu, biết rằng phản ứng xảy ra với hiệu suất 100%.

https://api.chinhxac.vn/media/public/90/97/9097ba10-ef10-451a-9c0d-be4701017622/6a36c7363234480c8533c682cdac128c.png

Si + 2NaOH + <svg style="display: inline-block; position: relative; top: -4px;" xmlns:xlink="http://www.w3.org/1999/xlink" width="2.985ex" height="2.509ex" viewBox="0 -791.3 1285.4 1080.4" role="img" focusable="false" xmlns="http://www.w3.org/2000/svg" aria-labelledby="MathJax-SVG-1-Title"><title id="MathJax-SVG-1-Title">H_{2}</title><defs aria-hidden="true"><path stroke-width="1" id="E1-MJMATHI-48" d="M228 637Q194 637 192 641Q191 643 191 649Q191 673 202 682Q204 683 219 683Q260 681 355 681Q389 681 418 681T463 682T483 682Q499 682 499 672Q499 670 497 658Q492 641 487 638H485Q483 638 480 638T473 638T464 637T455 637Q416 636 405 634T387 623Q384 619 355 500Q348 474 340 442T328 395L324 380Q324 378 469 378H614L615 381Q615 384 646 504Q674 619 674 627T617 637Q594 637 587 639T580 648Q580 650 582 660Q586 677 588 679T604 682Q609 682 646 681T740 680Q802 680 835 681T871 682Q888 682 888 672Q888 645 876 638H874Q872 638 869 638T862 638T853 637T844 637Q805 636 794 634T776 623Q773 618 704 340T634 58Q634 51 638 51Q646 48 692 46H723Q729 38 729 37T726 19Q722 6 716 0H701Q664 2 567 2Q533 2 504 2T458 2T437 1Q420 1 420 10Q420 15 423 24Q428 43 433 45Q437 46 448 46H454Q481 46 514 49Q520 50 522 50T528 55T534 64T540 82T547 110T558 153Q565 181 569 198Q602 330 602 331T457 332H312L279 197Q245 63 245 58Q245 51 253 49T303 46H334Q340 38 340 37T337 19Q333 6 327 0H312Q275 2 178 2Q144 2 115 2T69 2T48 1Q31 1 31 10Q31 12 34 24Q39 43 44 45Q48 46 59 46H65Q92 46 125 49Q139 52 144 61Q147 65 216 339T285 628Q285 635 228 637Z"></path><path stroke-width="1" id="E1-MJMAIN-32" d="M109 429Q82 429 66 447T50 491Q50 562 103 614T235 666Q326 666 387 610T449 465Q449 422 429 383T381 315T301 241Q265 210 201 149L142 93L218 92Q375 92 385 97Q392 99 409 186V189H449V186Q448 183 436 95T421 3V0H50V19V31Q50 38 56 46T86 81Q115 113 136 137Q145 147 170 174T204 211T233 244T261 278T284 308T305 340T320 369T333 401T340 431T343 464Q343 527 309 573T212 619Q179 619 154 602T119 569T109 550Q109 549 114 549Q132 549 151 535T170 489Q170 464 154 447T109 429Z"></path></defs><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)" aria-hidden="true"> <use xlink:href="#E1-MJMATHI-48" x="0" y="0"></use> <use transform="scale(0.707)" xlink:href="#E1-MJMAIN-32" x="1175" y="-213"></use></g></svg> O → <svg style="display: inline-block; position: relative; top: -4px;" xmlns:xlink="http://www.w3.org/1999/xlink" width="4.348ex" height="2.509ex" viewBox="0 -791.3 1871.9 1080.4" role="img" focusable="false" xmlns="http://www.w3.org/2000/svg" aria-labelledby="MathJax-SVG-1-Title"><title id="MathJax-SVG-1-Title">Na_{2}</title><defs aria-hidden="true"><path stroke-width="1" id="E1-MJMATHI-4E" d="M234 637Q231 637 226 637Q201 637 196 638T191 649Q191 676 202 682Q204 683 299 683Q376 683 387 683T401 677Q612 181 616 168L670 381Q723 592 723 606Q723 633 659 637Q635 637 635 648Q635 650 637 660Q641 676 643 679T653 683Q656 683 684 682T767 680Q817 680 843 681T873 682Q888 682 888 672Q888 650 880 642Q878 637 858 637Q787 633 769 597L620 7Q618 0 599 0Q585 0 582 2Q579 5 453 305L326 604L261 344Q196 88 196 79Q201 46 268 46H278Q284 41 284 38T282 19Q278 6 272 0H259Q228 2 151 2Q123 2 100 2T63 2T46 1Q31 1 31 10Q31 14 34 26T39 40Q41 46 62 46Q130 49 150 85Q154 91 221 362L289 634Q287 635 234 637Z"></path><path stroke-width="1" id="E1-MJMATHI-61" d="M33 157Q33 258 109 349T280 441Q331 441 370 392Q386 422 416 422Q429 422 439 414T449 394Q449 381 412 234T374 68Q374 43 381 35T402 26Q411 27 422 35Q443 55 463 131Q469 151 473 152Q475 153 483 153H487Q506 153 506 144Q506 138 501 117T481 63T449 13Q436 0 417 -8Q409 -10 393 -10Q359 -10 336 5T306 36L300 51Q299 52 296 50Q294 48 292 46Q233 -10 172 -10Q117 -10 75 30T33 157ZM351 328Q351 334 346 350T323 385T277 405Q242 405 210 374T160 293Q131 214 119 129Q119 126 119 118T118 106Q118 61 136 44T179 26Q217 26 254 59T298 110Q300 114 325 217T351 328Z"></path><path stroke-width="1" id="E1-MJMAIN-32" d="M109 429Q82 429 66 447T50 491Q50 562 103 614T235 666Q326 666 387 610T449 465Q449 422 429 383T381 315T301 241Q265 210 201 149L142 93L218 92Q375 92 385 97Q392 99 409 186V189H449V186Q448 183 436 95T421 3V0H50V19V31Q50 38 56 46T86 81Q115 113 136 137Q145 147 170 174T204 211T233 244T261 278T284 308T305 340T320 369T333 401T340 431T343 464Q343 527 309 573T212 619Q179 619 154 602T119 569T109 550Q109 549 114 549Q132 549 151 535T170 489Q170 464 154 447T109 429Z"></path></defs><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)" aria-hidden="true"> <use xlink:href="#E1-MJMATHI-4E" x="0" y="0"></use><g transform="translate(888,0)"> <use xlink:href="#E1-MJMATHI-61" x="0" y="0"></use> <use transform="scale(0.707)" xlink:href="#E1-MJMAIN-32" x="748" y="-213"></use></g></g></svg> <svg style="display: inline-block; position: relative; top: -4px;" xmlns:xlink="http://www.w3.org/1999/xlink" width="5.129ex" height="2.509ex" viewBox="0 -791.3 2208.4 1080.4" role="img" focusable="false" xmlns="http://www.w3.org/2000/svg" aria-labelledby="MathJax-SVG-1-Title"><title id="MathJax-SVG-1-Title">SiO_{3}</title><defs aria-hidden="true"><path stroke-width="1" id="E1-MJMATHI-53" d="M308 24Q367 24 416 76T466 197Q466 260 414 284Q308 311 278 321T236 341Q176 383 176 462Q176 523 208 573T273 648Q302 673 343 688T407 704H418H425Q521 704 564 640Q565 640 577 653T603 682T623 704Q624 704 627 704T632 705Q645 705 645 698T617 577T585 459T569 456Q549 456 549 465Q549 471 550 475Q550 478 551 494T553 520Q553 554 544 579T526 616T501 641Q465 662 419 662Q362 662 313 616T263 510Q263 480 278 458T319 427Q323 425 389 408T456 390Q490 379 522 342T554 242Q554 216 546 186Q541 164 528 137T492 78T426 18T332 -20Q320 -22 298 -22Q199 -22 144 33L134 44L106 13Q83 -14 78 -18T65 -22Q52 -22 52 -14Q52 -11 110 221Q112 227 130 227H143Q149 221 149 216Q149 214 148 207T144 186T142 153Q144 114 160 87T203 47T255 29T308 24Z"></path><path stroke-width="1" id="E1-MJMATHI-69" d="M184 600Q184 624 203 642T247 661Q265 661 277 649T290 619Q290 596 270 577T226 557Q211 557 198 567T184 600ZM21 287Q21 295 30 318T54 369T98 420T158 442Q197 442 223 419T250 357Q250 340 236 301T196 196T154 83Q149 61 149 51Q149 26 166 26Q175 26 185 29T208 43T235 78T260 137Q263 149 265 151T282 153Q302 153 302 143Q302 135 293 112T268 61T223 11T161 -11Q129 -11 102 10T74 74Q74 91 79 106T122 220Q160 321 166 341T173 380Q173 404 156 404H154Q124 404 99 371T61 287Q60 286 59 284T58 281T56 279T53 278T49 278T41 278H27Q21 284 21 287Z"></path><path stroke-width="1" id="E1-MJMATHI-4F" d="M740 435Q740 320 676 213T511 42T304 -22Q207 -22 138 35T51 201Q50 209 50 244Q50 346 98 438T227 601Q351 704 476 704Q514 704 524 703Q621 689 680 617T740 435ZM637 476Q637 565 591 615T476 665Q396 665 322 605Q242 542 200 428T157 216Q157 126 200 73T314 19Q404 19 485 98T608 313Q637 408 637 476Z"></path><path stroke-width="1" id="E1-MJMAIN-33" d="M127 463Q100 463 85 480T69 524Q69 579 117 622T233 665Q268 665 277 664Q351 652 390 611T430 522Q430 470 396 421T302 350L299 348Q299 347 308 345T337 336T375 315Q457 262 457 175Q457 96 395 37T238 -22Q158 -22 100 21T42 130Q42 158 60 175T105 193Q133 193 151 175T169 130Q169 119 166 110T159 94T148 82T136 74T126 70T118 67L114 66Q165 21 238 21Q293 21 321 74Q338 107 338 175V195Q338 290 274 322Q259 328 213 329L171 330L168 332Q166 335 166 348Q166 366 174 366Q202 366 232 371Q266 376 294 413T322 525V533Q322 590 287 612Q265 626 240 626Q208 626 181 615T143 592T132 580H135Q138 579 143 578T153 573T165 566T175 555T183 540T186 520Q186 498 172 481T127 463Z"></path></defs><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)" aria-hidden="true"> <use xlink:href="#E1-MJMATHI-53" x="0" y="0"></use> <use xlink:href="#E1-MJMATHI-69" x="645" y="0"></use><g transform="translate(991,0)"> <use xlink:href="#E1-MJMATHI-4F" x="0" y="0"></use> <use transform="scale(0.707)" xlink:href="#E1-MJMAIN-33" x="1079" y="-213"></use></g></g></svg> + <svg style="display: inline-block; position: relative; top: -4px;" xmlns:xlink="http://www.w3.org/1999/xlink" width="4.148ex" height="2.509ex" viewBox="0 -791.3 1785.9 1080.4" role="img" focusable="false" xmlns="http://www.w3.org/2000/svg" aria-labelledby="MathJax-SVG-1-Title"><title id="MathJax-SVG-1-Title">2H_{2}</title><defs aria-hidden="true"><path stroke-width="1" id="E1-MJMAIN-32" d="M109 429Q82 429 66 447T50 491Q50 562 103 614T235 666Q326 666 387 610T449 465Q449 422 429 383T381 315T301 241Q265 210 201 149L142 93L218 92Q375 92 385 97Q392 99 409 186V189H449V186Q448 183 436 95T421 3V0H50V19V31Q50 38 56 46T86 81Q115 113 136 137Q145 147 170 174T204 211T233 244T261 278T284 308T305 340T320 369T333 401T340 431T343 464Q343 527 309 573T212 619Q179 619 154 602T119 569T109 550Q109 549 114 549Q132 549 151 535T170 489Q170 464 154 447T109 429Z"></path><path stroke-width="1" id="E1-MJMATHI-48" d="M228 637Q194 637 192 641Q191 643 191 649Q191 673 202 682Q204 683 219 683Q260 681 355 681Q389 681 418 681T463 682T483 682Q499 682 499 672Q499 670 497 658Q492 641 487 638H485Q483 638 480 638T473 638T464 637T455 637Q416 636 405 634T387 623Q384 619 355 500Q348 474 340 442T328 395L324 380Q324 378 469 378H614L615 381Q615 384 646 504Q674 619 674 627T617 637Q594 637 587 639T580 648Q580 650 582 660Q586 677 588 679T604 682Q609 682 646 681T740 680Q802 680 835 681T871 682Q888 682 888 672Q888 645 876 638H874Q872 638 869 638T862 638T853 637T844 637Q805 636 794 634T776 623Q773 618 704 340T634 58Q634 51 638 51Q646 48 692 46H723Q729 38 729 37T726 19Q722 6 716 0H701Q664 2 567 2Q533 2 504 2T458 2T437 1Q420 1 420 10Q420 15 423 24Q428 43 433 45Q437 46 448 46H454Q481 46 514 49Q520 50 522 50T528 55T534 64T540 82T547 110T558 153Q565 181 569 198Q602 330 602 331T457 332H312L279 197Q245 63 245 58Q245 51 253 49T303 46H334Q340 38 340 37T337 19Q333 6 327 0H312Q275 2 178 2Q144 2 115 2T69 2T48 1Q31 1 31 10Q31 12 34 24Q39 43 44 45Q48 46 59 46H65Q92 46 125 49Q139 52 144 61Q147 65 216 339T285 628Q285 635 228 637Z"></path></defs><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)" aria-hidden="true"> <use xlink:href="#E1-MJMAIN-32" x="0" y="0"></use><g transform="translate(500,0)"> <use xlink:href="#E1-MJMATHI-48" x="0" y="0"></use> <use transform="scale(0.707)" xlink:href="#E1-MJMAIN-32" x="1175" y="-213"></use></g></g></svg> ↑

Từ phương trình phản ứng ta có:

https://api.chinhxac.vn/media/public/53/09/53090865-1afb-4f55-9003-fba0a5718e47/1caef0411eac45669eab1eb9e8ed8aa1.png

⇒ <svg style="display: inline-block; position: relative; top: -4px;" xmlns:xlink="http://www.w3.org/1999/xlink" width="3.9ex" height="2.009ex" viewBox="0 -576.1 1679.2 865.1" role="img" focusable="false" xmlns="http://www.w3.org/2000/svg" aria-labelledby="MathJax-SVG-1-Title"><title id="MathJax-SVG-1-Title">m_{Si}</title><defs aria-hidden="true"><path stroke-width="1" id="E1-MJMATHI-6D" d="M21 287Q22 293 24 303T36 341T56 388T88 425T132 442T175 435T205 417T221 395T229 376L231 369Q231 367 232 367L243 378Q303 442 384 442Q401 442 415 440T441 433T460 423T475 411T485 398T493 385T497 373T500 364T502 357L510 367Q573 442 659 442Q713 442 746 415T780 336Q780 285 742 178T704 50Q705 36 709 31T724 26Q752 26 776 56T815 138Q818 149 821 151T837 153Q857 153 857 145Q857 144 853 130Q845 101 831 73T785 17T716 -10Q669 -10 648 17T627 73Q627 92 663 193T700 345Q700 404 656 404H651Q565 404 506 303L499 291L466 157Q433 26 428 16Q415 -11 385 -11Q372 -11 364 -4T353 8T350 18Q350 29 384 161L420 307Q423 322 423 345Q423 404 379 404H374Q288 404 229 303L222 291L189 157Q156 26 151 16Q138 -11 108 -11Q95 -11 87 -5T76 7T74 17Q74 30 112 181Q151 335 151 342Q154 357 154 369Q154 405 129 405Q107 405 92 377T69 316T57 280Q55 278 41 278H27Q21 284 21 287Z"></path><path stroke-width="1" id="E1-MJMATHI-53" d="M308 24Q367 24 416 76T466 197Q466 260 414 284Q308 311 278 321T236 341Q176 383 176 462Q176 523 208 573T273 648Q302 673 343 688T407 704H418H425Q521 704 564 640Q565 640 577 653T603 682T623 704Q624 704 627 704T632 705Q645 705 645 698T617 577T585 459T569 456Q549 456 549 465Q549 471 550 475Q550 478 551 494T553 520Q553 554 544 579T526 616T501 641Q465 662 419 662Q362 662 313 616T263 510Q263 480 278 458T319 427Q323 425 389 408T456 390Q490 379 522 342T554 242Q554 216 546 186Q541 164 528 137T492 78T426 18T332 -20Q320 -22 298 -22Q199 -22 144 33L134 44L106 13Q83 -14 78 -18T65 -22Q52 -22 52 -14Q52 -11 110 221Q112 227 130 227H143Q149 221 149 216Q149 214 148 207T144 186T142 153Q144 114 160 87T203 47T255 29T308 24Z"></path><path stroke-width="1" id="E1-MJMATHI-69" d="M184 600Q184 624 203 642T247 661Q265 661 277 649T290 619Q290 596 270 577T226 557Q211 557 198 567T184 600ZM21 287Q21 295 30 318T54 369T98 420T158 442Q197 442 223 419T250 357Q250 340 236 301T196 196T154 83Q149 61 149 51Q149 26 166 26Q175 26 185 29T208 43T235 78T260 137Q263 149 265 151T282 153Q302 153 302 143Q302 135 293 112T268 61T223 11T161 -11Q129 -11 102 10T74 74Q74 91 79 106T122 220Q160 321 166 341T173 380Q173 404 156 404H154Q124 404 99 371T61 287Q60 286 59 284T58 281T56 279T53 278T49 278T41 278H27Q21 284 21 287Z"></path></defs><g stroke="currentColor" fill="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)" aria-hidden="true"> <use xlink:href="#E1-MJMATHI-6D" x="0" y="0"></use><g transform="translate(878,-155)"> <use transform="scale(0.707)" xlink:href="#E1-MJMATHI-53" x="0" y="0"></use> <use transform="scale(0.707)" xlink:href="#E1-MJMATHI-69" x="645" y="0"></use></g></g></svg> = 0,3.28 = 8,4 g

https://api.chinhxac.vn/media/public/d3/c1/d3c1a7f1-d73f-484a-be75-436a14fd71f9/ebd8d5c18bd0463dbe42d9b94b016aa7.png

Bài 6 trang 79 SGK Hóa 11